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A, Adsorption powers (Eads, measured in the eV) away from CH3OH, H2o, CO, Co2, H and H2 in almost any surface models. Following reaction, we sensed no oxidation away from platinum in both catalyst (than the brand new catalysts); but not, we performed to see oxidization out of a little bit of molybdenum, while the shown by age group from weakened portion in the high-times area. C, XPS spectra of one’s rare metal 4f and you will d, molybdenum 3d areas of 0.2percentPt/α-MoC both before and after experience of methanol/water vapour at the 190 °C for example time. Rare metal foil and you will rare metal oxide were used as the requirements. These XANES spectra advise that fees transfer away from rare metal to help you molybdenum try unchanged following reaction, which there is no indication of bulk stage oxidization within the α-MoC.
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